Reacción #536954

ord-73f2d5ae977749689f97ccef93bd284e

Ecuación de reacción

C[C@H]1[C@H](C)CC[C@]2(C(=O)O[C@@H]3O[C@H](CO[C@@H]4O[C@H](CO)[C@@H](O[C@@H]5O[C@@H](C)[C@H](O)[C@@H](O)[C@H]5O)[C@H](O)[C@H]4O)[C@@H](O)[C@H](O)[C@H]3O)CC[C@@]3(C)C(=CC[C@@H]4[C@@]5(C)C[C@@H](O)[C@H](O)[C@@](C)(CO)[C@@H]5[C@H](O)C[C@]43C)[C@H]12

madecassoside

→

C[C@H]1[C@H](C)CC[C@]2(C(=O)O[C@@H]3O[C@H](CO[C@@H]4O[C@H](CO)[C@@H](O[C@@H]5O[C@H](C)[C@H](O)[C@@H](O)[C@H]5O)[C@H](O)[C@H]4O)[C@@H](O)[C@H](O)[C@H]3O)CC[C@]3(C)C(=CC[C@@H]4[C@@]5(C)C[C@@H](O)[C@H](O)[C@@](C)(CO)[C@@H]5CC[C@]43C)[C@H]12

asiaticoside

Reactantes

—

alcohol

madecassoside

Reactivos

Ninguno

Disolventes

terminoloside

Condiciones de reacción

Condiciones detalladas

See reaction.notes.procedure_details.

Tratamiento posterior

1
OtroThe solution thus obtained
2
Filtraciónis filtered
3
Concentraciónconcentrated, in a reactor under reduced pressure, until an aqueous phase
4
Otrois obtained
5
Concentraciónaccording to the same principle as the preceding concentration
6
workup.ADDITIONby adding ethanol in order
7
Otroto obtain a stabilized aqueous-alcoholic solution

Procedimiento

The solution thus obtained is filtered and then concentrated, in a reactor under reduced pressure, until an aqueous phase is obtained, according to the same principle as the preceding concentration. It is then readjusted by adding ethanol in order to obtain a stabilized aqueous-alcoholic solution having a solids content of 200 g+/−20 per liter and an alcohol percentage of 35%+/−3.5% volume/volume. A prepurified phase rich in madecassoside and in terminoloside and still containing asiaticoside is thus obtained.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US08486900B2uspto-grants-2013_07