Reacción #531840

ord-0b6d3a93a6e742e4a401b8660f36094f

Ecuación de reacción

C=CCc1ccc(C)s1
2-allyl-5-methylthiophene
Cl[SiH](Cl)Cl
trichlorosilane
Cc1ccc(CCC[Si](Cl)(Cl)Cl)s1
2-(3-Trichlorosilylpropyl)-5-methylthiophene

Disolventes

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    OtroThe hydrosilylation reaction of Example 1

Procedimiento

The hydrosilylation reaction of Example 1 was repeated using 4.5 g of 2-allyl-5-methylthiophene in place of 2-allylthiophene, 2.5 g of anhydrous toluene, 5.0 g of trichlorosilane, and 50 mg of Platinum Catalyst. 2-(3-Trichlorosilylpropyl)-5-methylthiophene was obtained as a colorless liquid: 1H NMR (CDCl3) δ 6.60 (m, 2H); 2.88 (t, 2H, J=7.2 Hz); 2.47 (s, 3H); 1.95 (m, 2H); 1.47 (m, 2H).

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US08475937B2uspto-grants-2013_07