Reacción #531691

Ecuación de reacción

1,12-diaminododecane

N-methyl-1-(methylthio)-2-nitroethenamine

→

title compound

Rendimiento 60.0%

N-[1-(Methylamino)-2-nitroethenyl]-1,12-dodecanediamine

Rendimiento 60.0%

Disolventes

water

Condiciones de reacción

Tratamiento posterior

1. 1
   OtroThe solution was evaporated in vacuo
2. 2
   OtroThe appropriate eluate was evaporated

Procedimiento

A mixture of 1,12-diaminododecane (3 g) and N-methyl-1-(methylthio)-2-nitroethenamine (1.48 g) in water (50 ml) was stirred at room temperature for 20 hours. The solution was evaporated in vacuo and the residue chomatographed (silica/methanol). The appropriate eluate was evaporated to yield the title compound (1.8 g), mp. 123°-125°.

Fuente