Reacción #50855
ord-87da2cd7a1004668b0b227c1ea33b62b
Ecuación de reacción
Condiciones de reacción
Condiciones detalladas
See reaction.notes.procedure_details.
Tratamiento posterior
- 1Otrowas bubbled through the reaction mixture
Procedimiento
A solution of 81.5 grams (0.966 mole) 1-octene and 5.61 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl3 (4 millimoles) at 50° C. for 10 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 52 percent, inherent viscosity was 1.9 dl/gram. The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.