Reacción #502063

Ecuación de reacción

Perfluorobutane-1,4-disulfonic acid potassium salt

triphenylsulfonium bromide

Chloroform

→

bis(triphenylsulfonium) perfluorobutane-1,4-disulfonate

Disolventes

water

Condiciones de reacción

Tratamiento posterior

1. 1
   LavadoThe chloroform layer was washed several times with water
2. 2
   Secadodried over anhydrous sodium sulfate
3. 3
   Filtraciónfiltered
4. 4
   Otrothe filtrate evaporated to an oil stage
5. 5
   workup.ADDITIONEther was added to the oil
6. 6
   workup.STIRRINGthe mixture was stirred vigorously
7. 7
   OtroA white precipitate formed
8. 8
   FiltraciónThe mixture was filtered
9. 9
   Otrorecovered precipitate
10. 10
    Otrowas dried under vacuum
11. 11
    Otroresulting in a white powder

Procedimiento

Perfluorobutane-1,4-disulfonic acid potassium salt (2.5 g) was added to a solution of triphenylsulfonium bromide (3.5 g) in 150 ml of water. Chloroform (150 ml) was added and stirred for 5 hours. The chloroform layer was washed several times with water, dried over anhydrous sodium sulfate, filtered, and the filtrate evaporated to an oil stage. Ether was added to the oil and the mixture was stirred vigorously. A white precipitate formed. The mixture was filtered and recovered precipitate was dried under vacuum, resulting in a white powder; mp 155° C.

Fuente