Reacción #502059

ord-11d94e99141441139220eea2e5013c4c

Ecuación de reacción

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen
→
CC(C)CCCC(C)CCCC(C)CCCC(C)CCO
phytanol

Reactantes

C/C(=C\CO)CCC[C@H](C)CCC[C@H](C)CCCC(C)C
phytol
[H][H]
hydrogen

Reactivos

[Ni]
Raney nickel

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

Hydrogenation of phytol can also be accomplished using Raney nickel and hydrogen to yield phytanol as referenced in Bendavid, A., Burns, C. J., Leslie, D. F., Hashimoto, K., Ridley, D. D., Sandanayake, S., and Wieczorek L., J. Org. Chem. (2001), 66, 3709-3716; Kim, T., Chan, K. C, and Crooks, R. M., J. Am. Chem. Soc. (1997) 119, 189; and Jellum, E., Eldjarn, L., and Try, K., Acta Chem. Scand. (1966), 20, 2335.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US08088395B2uspto-grants-2012_01