Reacción #487527

ord-63837604956d4726a6cfde2531fe8fe5

Ecuación de reacción

$CCCCCCCC/C=C\CCCCCCCC(=O)Cl$

Oleoyl chloride

$CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O$

Erucic acid

→

CCCCCCCCC=CCCCCCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC

Compound D

Rendimiento 94.5%

Octadec-9-enoic acid docos-13-enyl ester

Rendimiento 94.5%

Reactantes

—

compounds D2

—

$CCCCCCCC/C=C\CCCCCCCC(=O)Cl$

Oleoyl chloride

$CCCCCCCC/C=C\CCCCCCCCCCCC(=O)O$

Erucic acid

—

compound D

Reactivos

Ninguno

Disolventes

Ethyl acetate Hexane

Condiciones de reacción

Condiciones detalladas

See reaction.notes.procedure_details.

Procedimiento

Compound D was prepared from Oleoyl chloride and Erucic acid following the general procedure discussed before and as shown in FIG. 9. Pure compound D was a colorless oil obtained by column chromatography with Ethyl acetate/Hexane=1:40. Reaction conditions for branched derivative compounds D2, D3, and D4 are also shown below.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US08741822B2uspto-grants-2014_06