Reacción #486368

Ecuación de reacción

2,5-dianilinoterephthalic acid

sulfuric acid

→

quinacridone

Disolventes

water

water

Condiciones de reacción

Tratamiento posterior

1. 1
   TemperaturaThen, the mixture was cooled to 80° C.
2. 2
   workup.ADDITIONThen, the mixture was poured into 500 parts of ice-
3. 3
   Filtraciónthe mixture was filtered
4. 4
   Lavadowashed with water
5. 5
   Otrodried
6. 6
   Otroto give 5.83 parts (93.5% of the

Procedimiento

A 200-ml flask was charged with 6.96 parts of the 2,5-dianilinoterephthalic acid obtained in Example 29 and 70 parts of sulfuric acid having a concentration of 98%, and while the mixture was stirred, the mixture was maintained at 160° C. for 5 hours. Then, the mixture was cooled to 80° C. or lower, and 50 parts of water was gradually added over 4 hours. Then, the mixture was poured into 500 parts of ice-containing water at one stroke, and the mixture was filtered, washed with water and dried to give 5.83 parts (93.5% of the theoretical yield) of an unsubstituted quinacridone.

Fuente