Reacción #47128

Ecuación de reacción

oxygen

p-xylene

N-acetoxyphthalimide

acetic acid

→

terephthalic acid

p-toluic acid

Condiciones de reacción

Procedimiento

A mixture of 2 mmol of p-xylene, 0.2 mmol of N-acetoxyphthalimide, 0.01 mmol of cobalt(II) acetate and 2 ml of acetic acid was stirred at 100° C. in an atmosphere of oxygen gas (1 atm=0.1 MPa) for 14 hours and thereby yielded terephthalic acid and p-toluic acid in yields of 89% and 1%, respectively.

Fuente