Reacción #465953

ord-c4b88dc8fc2f43d4a6be06585468b591

Ecuación de reacción

CCCCCCOC(C)(C)C
hexyl t-butyl ether
CC(C)(C)O
t-butanol
CCCCCCO
1-hexanol
N#N
N2
CCCCCCO
hexanol
CC(C)(C)OC(C)(C)C
t-Butyl Ether

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

300 mmoles of t-butanol, 100 mmoles of 1-hexanol and 2.5 g of Ti-Si-catalyst powder are stirred in a 100 ml autoclave at a pressure of 40 bar N2 and a temperature of 150° C. over a period of 17 h, 17% of n hexanol were converted into hexyl t-butyl ether with a selectivity of 90%.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US06297180B1uspto-grants-2001_10