Reacción #465952

ord-6a5710d67e814d708dc3e64c5f91b38a

Ecuación de reacción

CCCCCCOC(C)(C)C
hexyl-t-butyl ether
C=C(C)C
i-butene
CCCCCCO
1-hexanol
N#N
N2
CCCCCCO
n-hexanol
CC(C)(C)OC(C)(C)C
t-Butyl Ether

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

300 mmoles of i-butene, 100 mmoles of 1-hexanol and 2.5 g of Ti-Si-catalyst powder are stirred in a 100 ml autoclave at a pressure of 40 bar N2 and a temperature of 150° C. over a period of 18 h, 62% of n-hexanol were converted into hexyl-t-butyl ether with a selectivity of 92%.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US06297180B1uspto-grants-2001_10