Reacción #458103

ord-25f192e94eca461997ad4dab806372ee

Ecuación de reacción

CN=C(Cl)c1ccc([N+](=O)[O-])cc1
N-methyl 4-nitrobenzimidoyl chloride
O=S(=O)(O)Cl
chlorosulfonic acid
COC(=O)Cc1cc(C)cn1C
methyl 1,4-dimethyl-1H-pyrrole-2-acetate
[O-][Cl+3]([O-])([O-])O
perchloric acid
→
CN=C(c1ccc([N+](=O)[O-])cc1)c1c(C)cc(CC(=O)OC)n1C.[O-][Cl+3]([O-])([O-])O
title compound
CN=C(c1ccc([N+](=O)[O-])cc1)c1c(C)cc(CC(=O)OC)n1C.[O-][Cl+3]([O-])([O-])O
Methyl 1,4-Dimethyl-5-[(methylimino)(4-nitrophenyl)methyl]-1H-pyrrole-2-acetate Perchlorate

Reactantes

CN=C(Cl)c1ccc([N+](=O)[O-])cc1
N-methyl 4-nitrobenzimidoyl chloride
O=S(=O)(O)Cl
chlorosulfonic acid
COC(=O)Cc1cc(C)cn1C
methyl 1,4-dimethyl-1H-pyrrole-2-acetate
[O-][Cl+3]([O-])([O-])O
perchloric acid

Reactivos

Ninguno

Disolventes

—
alcohol

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

The title compound was prepared as in Example X from N-methyl 4-nitrobenzimidoyl chloride (2.0 g, 10.1 mmole) in alcohol free chloroform (30 ml), chlorosulfonic acid (0.12 g, 1 mmole), methyl 1,4-dimethyl-1H-pyrrole-2-acetate (1.68 g, 10.06 mmole) and 70% perchloric acid (1.57 g, 11 mmole) to yield 2.77 g (65%) of a yellow solid, m.p. 108° C. (dec).

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04528382uspto-grants-1985_07