Reacción #439227

Ecuación de reacción

propargyl bromide

sodium carbonate

n-tetradecylamine

→

Propargyl-n-tetradecylamine

Disolventes

acetone

acetone

Condiciones de reacción

Tratamiento posterior

1. 1
   Temperaturathe suspension is heated to reflux
2. 2
   Temperaturathe mixture is subsequently heated
3. 3
   Temperaturaat reflux for 2 hours
4. 4
   OtroAfter aqueous working-up, the product is obtained in the form of a brown oil

Procedimiento

5 g (47 mmol) of anhydrous sodium carbonate are added to a solution of 10.0 g (47 mmol) of n-tetradecylamine in 100 ml of absolute acetone, and the suspension is heated to reflux. At that temperature 5.9 g (50 mmol) of propargyl bromide in 50 ml of acetone are then added dropwise and the mixture is subsequently heated at reflux for 2 hours. After aqueous working-up, the product is obtained in the form of a brown oil having a purity of >90%.

Fuente