Reacción #43599

ord-d7c270c11b2d48df9ab6c3a0d6b5eae8

Ecuación de reacción

NC1CCN(CC2Cn3c(=O)ccc4ncc(Cl)c2c43)CC1
4-[(4-amino-1-piperidinyl)methyl]-3-chloro-4,5-dihydro-7H-pyrrolo[3,2,1-de]-1,5-naphthyridin-7-one
O=Cc1ccc2c(c1)NC(=O)CO2
3-oxo-3,4-dihydro-2H-benzo[1,4]oxazine-6-carboxaldehyde
Cl.O=C1COc2ccc(CNC3CCN(CC4Cn5c(=O)ccc6ncc(Cl)c4c65)CC3)cc2N1
title compound
Rendimiento 69.0%
Cl.O=C1COc2ccc(CNC3CCN(CC4Cn5c(=O)ccc6ncc(Cl)c4c65)CC3)cc2N1
3-Chloro-4-[(4-{[(3-oxo-3,4-dihydro-2H-1,4-benzoxazin-6-yl)methyl]amino}-1-piperidinyl)methyl]-4,5-dihydro-7H-pyrrolo[3,2,1-de]-1,5-naphthyridin-7-one Hydrochloride
Rendimiento 69.0%

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

The free base of the title compound was synthesised from 4-[(4-amino-1-piperidinyl)methyl]-3-chloro-4,5-dihydro-7H-pyrrolo[3,2,1-de]-1,5-naphthyridin-7-one and 3-oxo-3,4-dihydro-2H-benzo[1,4]oxazine-6-carboxaldehyde (for a synthesis see WO2002056882, Example 5(b)), according to the general method of Example 2(h), in 69% yield.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US07732461B2uspto-grants-2010_06