Reacción #433588

ord-5370d7db4ff949b28a752734447fc010

Ecuación de reacción

c1ccc2ncncc2c1
quinazoline
Nc1cc(Cl)c(Cl)cc1F
3,4-dichloro-6-fluoroaniline
O=[N+]([O-])c1ccc2ncnc(Cl)c2c1
4-chloro-6-nitroquinazoline
O=[N+]([O-])c1ccc2ncnc(Nc3cc(Cl)c(Cl)cc3F)c2c1
4-[(3,4-dichloro-6-fluorophenyl)amino]-6-nitroquinazoline

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

In one particular, which includes a quinazoline that is substituted by one reactive group at position 6 thereof, 3,4-dichloro-6-fluoroaniline is reacted with 4-chloro-6-nitroquinazoline, so as to produce 4-[(3,4-dichloro-6-fluorophenyl)amino]-6-nitroquinazoline, which is reduced, by means of an ethanolic solution of hydrazine hydrate and Raney®Nickel, so as to produce 4-[(3,4-dichloro-6-fluorophenyl)amino]-6-aminoquinazoline. Then, the 4-[(3,4-dichloro-6-fluorophenyl)amino]-6-aminoquinazoline is reacted with a carbon-11 labeled acryloyl chloride so as to produce a carbon-11 labeled N-{4-[(3,4-dichloro-6-fluorophenyl)amino]quinazoline-6-yl}acrylamide (carbon-11 labeled Compound 3).

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US07172749B2uspto-grants-2007_02