Reacción #4045

Ecuación de reacción

perfluoro-2-methyl-3-oxahexanoyl fluoride

sodium trimethylsilanolate

→

Sodium perfluoro-2-methyl-3-oxahexanoate

Rendimiento 69.3%

Disolventes

tetrahydrofuran

Condiciones de reacción

Tratamiento posterior

1. 1
   Otroa 2 h reaction time

Procedimiento

The procedure of Example 1 was followed using perfluoro-2-methyl-3-oxahexanoyl fluoride (16.6 g, 50 mmol), sodium trimethylsilanolate (5.6 g, 50 mmol), and dry tetrahydrofuran (100 mL), and a 2 h reaction time. Sodium perfluoro-2-methyl-3-oxahexanoate (12.2 g, 69% yield) was isolated as a white solid: The 19F NMR data were the same as reported in Example 15.

Fuente