Reacción #4016

Ecuación de reacción

1,1,1-triethoxyethane

N-chlorosuccinimide

→

2-chloro-1,1,1-triethoxyethane

Rendimiento 77.1%

Disolventes

carbon tetrachloride

Condiciones de reacción

Tratamiento posterior

1. 1
   Otroirradiated with an ultraviolet lamp
2. 2
   Otrosubsided upon completion of the reaction
3. 3
   FiltraciónThe precipitated succinimide byproduct was filtered off
4. 4
   Concentraciónthe filtrate was concentrated
5. 5
   Otroto remove carbon tetrachloride
6. 6
   workup.DISTILLATIONThe residual liquid was distilled

Procedimiento

A mixture of 1,1,1-triethoxyethane (97.3 g) and N-chlorosuccinimide (88.1 g) in carbon tetrachloride (600 ml) was warmed to 40° C. and then irradiated with an ultraviolet lamp. The reaction became exothermic and then subsided upon completion of the reaction. The precipitated succinimide byproduct was filtered off and the filtrate was concentrated to remove carbon tetrachloride. The residual liquid was distilled to obtain pure 2-chloro-1,1,1-triethoxyethane (91.0 g; b.p. 91° C./25 mm).

Fuente