Reacción #334895
ord-02a49089b68b4c768b9d92d5910ce35c
Ecuación de reacción
ethylene carbonate
dipropylene glycol
→
ethylene carbonate
Rendimiento 100.0%
carbon dioxide
Rendimiento 14.7%
Reactantes
Reactivos
Condiciones de reacción
Temperatura
175°CELSIUS
Condiciones detalladas
See reaction.notes.procedure_details.
Procedimiento
A 10:1 mole ratio of ethylene carbonate to dipropylene glycol is heated with stirring under a nitrogen atmosphere for 4 hours at 175° C. using 0.5 percent sodium stannate trihydrate as catalyst to give 100 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 14.7 percent carbon dioxide The catalyst is removed as in Example 1.