Reacción #334891
ord-d55c128e493543ae96f7edf2646d3d77
Ecuación de reacción
ethylene carbonate
→
ethylene carbonate
Rendimiento 97.5%
carbon dioxide
Rendimiento 23.7%
Reactantes
Reactivos
Disolventes
Condiciones de reacción
Temperatura
175°CELSIUS
Condiciones detalladas
See reaction.notes.procedure_details.
Procedimiento
A 10:1 mole ratio of ethylene carbonate and diethylene glycol is heated with stirring under a nitrogen atmosphere for 3 hours at 175° C. using 0.5 percent Na2SnO3.3H2O as catalyst to give 97.5 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 23.7 percent carbon dioxide. The catalyst is removed as in Example 1.