Reacción #334887

ord-3d6694b4125645898566ca7e0ef4e948

Ecuación de reacción

O=C1OCCO1
ethylene carbonate
O=C1OCCO1
ethylene carbonate
Rendimiento 100.0%
O=C=O
carbon dioxide
Rendimiento 25.8%

Condiciones de reacción

Temperatura
135°CELSIUS
Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

A 10:1 mole ratio of ethylene carbonate:monoethylene glycol is heated with stirring under a nitrogen atmosphere for 24 hours at 135° C. using 1.0 percent Na2SnO3.3H2O as catalyst to give a 100 percent ethylene carbonate conversion to a poly(alkylene carbonate) polyol with 25.8 percent carbon dioxide.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04709069uspto-grants-1987_11