Reacción #318925

ord-6935791bf87f43eca19ae100afb76aea

Ecuación de reacción

O=[N+]([O-])c1ccc(-c2ccccc2S(=O)(=O)c2ccccc2-c2ccc([N+](=O)[O-])cc2)cc1
4-nitrophenylphenyl sulfone
O=[N+]([O-])c1ccccc1
nitrobenzene
[Na+].[S-]c1ccccc1
sodium thiophenolate
→
O=[N+]([O-])c1ccc(-c2ccccc2Sc2ccccc2-c2ccc([N+](=O)[O-])cc2)cc1
4-Nitrophenylphenyl Sulfide

Reactantes

O=[N+]([O-])c1ccc(-c2ccccc2S(=O)(=O)c2ccccc2-c2ccc([N+](=O)[O-])cc2)cc1
4-nitrophenylphenyl sulfone
O=[N+]([O-])c1ccccc1
nitrobenzene
[Na+].[S-]c1ccccc1
sodium thiophenolate

Reactivos

Ninguno

Disolventes

O
water

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

An amount of 21.4 g (0.08 mole) of the thus obtained 4-nitrophenylphenyl sulfone was dissolved in a two phase solvent composed of a mixture of 80 g of nitrobenzene and 80 g of water, and was reacted with sodium thiophenolate in the same manner as in Example 1.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04849138uspto-grants-1989_07