Reacción #2681

Ecuación de reacción

tri-n-decylmethylchloride

trimethylaluminum

→

tri-n-decylmethylmethane

Rendimiento 75.0%

Disolventes

methylene chloride

Condiciones de reacción

Tratamiento posterior

1. 1
   Temperaturato warm to room temperature
2. 2
   OtroThe mixture was slowly quenched with 50 ml of water
3. 3
   Lavadoby washing with 1 liter of a 10% HCl solution
4. 4
   SecadoThe organic layer was dried with magnesium sulfate
5. 5
   Otrothe solvent was evaporated

Procedimiento

One mole of tri-n-decylmethylchloride was added to 0.75 liters of methylene chloride and the solution was blanketed with nitrogen and cooled to 0° C. 0.33 moles of trimethylaluminum was then added and the mixture was allowed to warm to room temperature. The mixture was slowly quenched with 50 ml of water followed by washing with 1 liter of a 10% HCl solution. The organic layer was dried with magnesium sulfate and the solvent was evaporated to give tri-n-decylmethylmethane after vacuum distillation at 225 C/0.5 torr. The yield was 75%.

Fuente