Reacción #2680

Ecuación de reacción

HCl

tri-n-decylcarbinol

calcium chloride

→

tri-n-decylmethylchloride

Rendimiento 90.0%

Disolventes

methylene chloride

Condiciones de reacción

Tratamiento posterior

1. 1
   LavadoThe product mixture is then washed with 1 liter of a 10% sodium carbonate solution
2. 2
   SecadoThe organic layer is dried with magnesium sulfate
3. 3
   Otrothe methylene chloride evaporated off

Procedimiento

One mole of tri-n-decylcarbinol was added to a mixture of 0.2 liters of methylene chloride and 0.32 moles calcium chloride. Approximately 1.5 moles of HCl gas was slowly bubbled through the solution. The product mixture is then washed with 1 liter of a 10% sodium carbonate solution. The organic layer is dried with magnesium sulfate and the methylene chloride evaporated off to give a 90% yield of tri-n-decylmethylchloride.

Fuente