Reacción #2501397

Ecuación de reacción

Di-(2-thienyl)sulfide

diphenyliodonium triflate

ethyl ether

→

title compound

Rendimiento 78.0%

di-(2-thienyl)phenylsulfonium triflate

Rendimiento 78.0%

Disolventes

water

Condiciones de reacción

Tratamiento posterior

1. 1
   TemperaturaAfter cooling down
2. 2
   Otrothe mixture vigorously stirred overnight
3. 3
   FiltraciónFiltration
4. 4
   Lavadowashing with ethyl ether
5. 5
   Otroyielded a brown solid, which
6. 6
   Filtraciónthe solution filtered
7. 7
   Otrothe water removed in vacuo
8. 8
   Filtraciónthe mixture filtered
9. 9
   Lavadothe residue washed with ethyl ether

Procedimiento

Di-(2-thienyl)sulfide (2.1 g, 0.0104 mole), diphenyliodonium triflate (5.8 g, 0.0135 mole) and copper benzoate (0.08 g, 0.003 mole) are heated without solvent for 3 hours at 120-145° C. under a nitrogen atmosphere. After cooling down, 75 ml ethyl ether was added and the mixture vigorously stirred overnight to achieve solidification. Filtration and washing with ethyl ether yielded a brown solid, which was dissolved in hot water, the solution filtered and the water removed in vacuo. The resulting white solid was stirred in 50 ml ethyl ether for 24 hours, the mixture filtered and the residue washed with ethyl ether, yielding 3.4 g (78%) of the title compound, di(2-thienyl)phenylsulfonium triflate. The structure was confirmed by 1H/13C NMR spectroscopy.

Fuente