Reacción #2380007

ord-2ed6cd749e6a498499d8ba54b4904828

Ecuación de reacción

[Na+].[OH-]
sodium hydroxide
CC(=O)Nc1cc(N)ccc1N=Nc1ccc2c(S(=O)(=O)O)cccc2c1S(=O)(=O)O
2-(2-acetylamino-4-aminophenylazo)naphthalene-1,5-disulfonic acid
Clc1nc(Cl)nc(Cl)n1
cyanuric chloride
O=P([O-])([O-])O.[Na+].[Na+]
disodium hydrogen phosphate
→
CC(=O)Nc1cc(Nc2nc(Cl)nc(Cl)n2)ccc1N=Nc1ccc2c(S(=O)(=O)O)cccc2c1S(=O)(=O)O
2-[2-acetylamino-4-(4,6-dichloro-1,3,5-triazin-2-ylamino)phenylazo]naphthalene-1,5-disulfonic acid

Reactantes

[Na+].[OH-]
sodium hydroxide
CC(=O)Nc1cc(N)ccc1N=Nc1ccc2c(S(=O)(=O)O)cccc2c1S(=O)(=O)O
2-(2-acetylamino-4-aminophenylazo)naphthalene-1,5-disulfonic acid
—
48
Clc1nc(Cl)nc(Cl)n1
cyanuric chloride
O=P([O-])([O-])O.[Na+].[Na+]
disodium hydrogen phosphate

Reactivos

Ninguno

Disolventes

O
water
O
water

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

19 parts of cyanuric chloride are stirred vigorously into 50 parts of water, with addition of a wetting agent and 5 parts of disodium hydrogen phosphate, at a temperature of 0° C. A neutral solution of 48 parts of 2-(2-acetylamino-4-aminophenylazo)naphthalene-1,5-disulfonic acid in 450 parts of water is added dropwise, during which the pH is kept at a value of 4.5 by addition of sodium hydroxide solution. A solution of 2-[2-acetylamino-4-(4,6-dichloro-1,3,5-triazin-2-ylamino)phenylazo]naphthalene-1,5-disulfonic acid is obtained (solution 2).

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US05684138uspto-grants-1997_11