Reacción #2358556

ord-360c77676cd24a36a757370bc8274e84

Ecuación de reacción

N#Cc1ccc(B(O)O)cc1
4-cyanophenyl boronic acid
Brc1ccc2cc(-c3ccc4c5c(cccc35)-c3c-4c(-c4ccccc4)c4ccccc4c3-c3ccccc3)ccc2c1
3-(6-bromonaphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene
N#Cc1ccc(-c2ccc3cc(-c4ccc5c6c(cccc46)-c4c-5c(-c5ccccc5)c5ccccc5c4-c4ccccc4)ccc3c2)cc1
Compound 5-12
N#Cc1ccc(-c2ccc3cc(-c4ccc5c6c(cccc46)-c4c-5c(-c5ccccc5)c5ccccc5c4-c4ccccc4)ccc3c2)cc1
3-(6-(4-cyanophenyl)naphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

It was carried out in a similar manner as Synthesis Example 1 except that 4-cyanophenyl boronic acid was employed instead of 9,9-dimethyl-9H-fluorene-2-yl boronic acid, and that 3-(6-bromonaphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene was employed instead of 3-bromo-7,12-dibenzo[k]fluoranthene in Synthesis Example 1 to obtain 3-(6-(4-cyanophenyl)naphthalen-2-yl)-7,12-diphenylbenzo[k]fluoranthene (Compound 5-12).

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US09120748B2uspto-grants-2015_09