Reacción #2195483

ord-f132cab694994be289e1642ae04a3dc8

Ecuación de reacción

CC(C)(C)c1ccc(S(=O)c2ccc(C(C)(C)C)cc2)cc1
bis(4-tert-butylphenyl) sulfoxide
CC(C)(C)c1ccc(Br)cc1
4-tert-butylbromobenzene
CC(C)(C)c1ccc([S+](c2ccc(C(C)(C)C)cc2)c2ccc(C(C)(C)C)cc2)cc1.[Br-]
tris(4-tert-butylphenyl)sulfonium bromide

Disolventes

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    OtroThe target compound was obtained
  2. 2
    Otrothe procedure of Synthesis Example 1 aside
  3. 3
    Otroin Synthesis Example 1
  4. 4
    Extracciónfor extraction

Procedimiento

The target compound was obtained by following the procedure of Synthesis Example 1 aside from using bis(4-tert-butylphenyl) sulfoxide instead of the diphenyl sulfoxide and 4-tert-butylbromobenzene instead of the chlorobenzene in Synthesis Example 1, and increasing the amount of water for extraction.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US07514202B2uspto-grants-2009_04