Reacción #215623

Ecuación de reacción

1H-1,2,4-triazole

tetrabutylammonium hydroxide

→

tetrabutylammonium 1H-1,2,4-triazole

Disolventes

Condiciones de reacción

Tratamiento posterior

1. 1
   OtroThe mixture was evaporated in vacuo and 50 ml portions of toluene
2. 2
   workup.ADDITIONwere added several times
3. 3
   Otroto remove the water
4. 4
   Otroobtained azeotropically
5. 5
   OtroFinally the viscous product was dried in high vacuum until constant in weight
6. 6
   OtroThere was obtained 31.5 g of a yellowish, viscous mass

Procedimiento

7 g of 1H-1,2,4-triazole were dissolved in 65 g of a commercial 40% aqueous solution of tetrabutylammonium hydroxide. The mixture was evaporated in vacuo and 50 ml portions of toluene were added several times to remove the water obtained azeotropically. Finally the viscous product was dried in high vacuum until constant in weight. There was obtained 31.5 g of a yellowish, viscous mass.

Fuente