Reacción #2122502

Ecuación de reacción

picolinic acid

2-phenylbenzoxazole Iridium chloride

→

Bis(2-phenylbenzooxazole) Iridium picolinate

Disolventes

dichloromethane

Condiciones de reacción

Tratamiento posterior

1. 1
   TemperaturaThe mixture was heated
2. 2
   Temperaturato reflux under nitrogen in an oil bath overnight (17.5 hrs.)
3. 3
   OtroReaction mixture
4. 4
   Filtraciónthe yellow precipitate was filtered off via vacuum
5. 5
   workup.DISSOLUTIONThe precipitate was dissolved in dichloromethane
6. 6
   Otrowas removed

Procedimiento

0.52 mmol (0.064 g) of picolinic acid was added to a room-temperature solution of 0.14 mmol 2-phenylbenzoxazole Iridium chloride dimer (0.18 g) in 20 mL of dichloromethane. The mixture was heated to reflux under nitrogen in an oil bath overnight (17.5 hrs.). Reaction mixture was cooled to room temperature, and the yellow precipitate was filtered off via vacuum. The precipitate was dissolved in dichloromethane and transferred to a vial, and the solvent was removed. Emission spectrum is in FIG. 46.

Fuente