Reacción #2088475

ord-53b2374ab9584e24b75c3e5f60f38413

Ecuación de reacción

O=CN1C(=O)c2ccccc2S1(=O)=O
O=CN1C(=O)c2ccccc2S1
CC(C)(C)OC(=O)N1CCc2cc(Br)cc(OCc3ccccc3)c2C1
CC(C)(C)OC(=O)N1CCc2
CC[Si](CC)CC
CC[Si](CC)CC
→
CC(C)(C)OC(=O)N1CCc2cc(C=O)cc(OCc3ccccc3)c2C1
CC(C)(C)OC(=O)N1CCc2

Reactantes

O=CN1C(=O)c2ccccc2S1(=O)=O
O=CN1C(=O)c2ccccc2S1(=O)=O
CC(C)(C)OC(=O)N1CCc2cc(Br)cc(OCc3ccccc3)c2C1
CC(C)(C)OC(=O)N1CCc2cc(Br)cc(O
CC[Si](CC)CC
CC[Si](CC)CC

Reactivos

CC(=O)[O][Pd][O]C(C)=O
Pd(OAc)2
c1ccc(-c2c3ccccc3cc3ccccc23)cc1
9-Phenylanthracene
CCN(C(C)C)C(C)C
DIPEA
C1CCCC1.C[C@@H](C1CCCC1c1ccccc1P(c1ccccc1)c1ccccc1)P(C1C[C@H]2CC[C@@H]1C2)C1C[C@@H]2CC[C@H]1C2.[Fe]
Walphos SL-W022-2

Disolventes

CN(C)C=O
DMF

Condiciones de reacción

Temperatura
80°CELSIUS

Fuente

DOI: 10.1038/s4155739k HTE dataset from Pfizer