Reacción #2014276

ord-79c6db1a90544de68e5b9d85966e9135

Ecuación de reacción

OC(c1ccccc1)(c1ccccc1)C12CCN(CC1)CC2
1-azabicyclo[2.2.2]oct-4-yl(diphenyl)methanol
Fc1ccc(OCCCBr)cc1
3-bromopropyl 4-fluorophenyl ether
OC(c1ccccc1)(c1ccccc1)C12CC[N+](CCCOc3ccc(F)cc3)(CC1)CC2.[Br-]
desired product
Rendimiento 43.7%
OC(c1ccccc1)(c1ccccc1)C12CC[N+](CCCOc3ccc(F)cc3)(CC1)CC2.[Br-]
1-{3-[(4-fluorophenyl)oxy]propyl}-4-[hydroxy(diphenyl)methyl]-1-azoniabicyclo[2.2.2]octane bromide
Rendimiento 43.7%

Disolventes

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    Otrowere reacted

Procedimiento

Following the general procedure outlined in Example 3, 1-azabicyclo[2.2.2]oct-4-yl(diphenyl)methanol (0.0182 g, 0.0621 mmol) and 3-bromopropyl 4-fluorophenyl ether (0.0173 g, 0.0742 mmol) in 2 CH3CN/3 CHCl3 (4.0 mL) were reacted to give the desired product (0.0143 g, 43.7%). EI-MS m/z 446 (M+) Rt (1.96 min).

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US08183257B2uspto-grants-2012_05