Reacción #1859765

Ecuación de reacción

2-(allyloxy)-N,N-dimethylethanamine

trimethoxysilane

→

target compound

Rendimiento 86.0%

N,N-dimethyl-2-(3-(trimethoxysilyl)propoxy)ethanamine

Rendimiento 86.0%

Disolventes

toluene

Condiciones de reacción

Tratamiento posterior

1. 1
   OtroUpon completion of reaction
2. 2
   Otroafter removing the solvent
3. 3
   workup.DISTILLATIONthrough distillation under reduced pressure

Procedimiento

After adding toluene (200 mL) to a round-bottom flask containing 2-(allyloxy)-N,N-dimethylethanamine (0.398 mol) and dissolving trimethoxysilane (0.398 mol), a commercially available platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane solution was added and the mixture was stirred for 24 hours. Upon completion of reaction, after removing the solvent through distillation under reduced pressure, 0.342 mol (yield: 86%) of the target compound was obtained by extracting with water and diethyl ether. 1H and 13C NMR spectroscopic data of the purified N,N-dimethyl-2-(3-(trimethoxysilyl)propoxy)ethanamine are as follows.

Fuente