Reacción #1824335

ord-775a5bbb9d474ab4bd1d342a0f3a4477

Ecuación de reacción

CC(C)(C)CC=CCC1=C(O)C(=O)c2ccccc2C1=O
2-(5,5-dimethylhex-2-enyl)-3-hydroxynaphthalene- 1,4-dione
[H][H]
hydrogen
→
CC(C)(C)CCCCC1=C(O)C(=O)c2ccccc2C1=O
title compound
CC(C)(C)CCCCC1=C(O)C(=O)c2ccccc2C1=O
2-(5.5-dimethylhexyl)-3-hydroxy-naphthalene-1,4-dione

Reactantes

CC(C)(C)CC=CCC1=C(O)C(=O)c2ccccc2C1=O
2-(5,5-dimethylhex-2-enyl)-3-hydroxynaphthalene- 1,4-dione
[H][H]
hydrogen

Reactivos

[Pd]
Pd/C

Disolventes

CCOC(C)=O
ethyl acetate

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

2-(5,5-dimethylhex-2-enyl)-3-hydroxynaphthalene- 1,4-dione(3 91 mg) prepared in Example 45 was dissolved in ethyl acetate (15 ml) and hydrogenated as in Example 1(c) using hydrogen and 100 mg of Pd/C catalyst to provide 371 mg title compound.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US05962002uspto-grants-1999_10