Reacción #1824319

ord-9e69cea78c02407da574bd8e8b459cc3

Ecuación de reacción

O=C([O-])[O-].[Ca+2]
calcium carbonate
CC(=O)O
acetic acid
CC(=O)O
acetic acid
CC(=O)[O-].CC(=O)[O-].[Ca+2]
calcium acetate

Reactivos

Ninguno

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    Otro2.7 L of liquid was collected
  2. 2
    OtroThe liquid collected
  3. 3
    Otroas was shown by evaporation of a 10-mL sample at 105° C

Procedimiento

(EXAMPLE 18) In a similar experiment, 200 g of the ash was mixed with 3.0 L of 20% (v/v) or 21% (w/w) acetic acid. That amount of acetic acid corresponded to 4.2 times the stoichiometric proportion of calcium carbonate in the ash. The slurry was agitated and left overnight at room temperature. 2.7 L of liquid was collected. The liquid collected contained 9.2±0.2% solids (based on two separate measurements), as was shown by evaporation of a 10-mL sample at 105° C. The theoretical amount of calcium acetate formed in the reaction mixture would have been 6.6% by weight. The elemental calcium content in the dried extract was determined to be 19.2±0.4% (based on two independent measurements), translating into 76% Ca(CH3COO)2, or 85% Ca(CH3COO)2.H2O.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US05961941uspto-grants-1999_10