Reacción #170341

ord-c235b749b3fb4793959afaef71f0ab31

Ecuación de reacción

Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)O)cn1
6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid
Cl.FC1(F)CCNCC1
4,4-difluoropiperidine hydrochloride
Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)N2CCC(F)(F)CC2)cn1
title compound
Rendimiento 98.0%
Cc1onc(-c2ccccc2)c1COc1ccc(C(=O)N2CCC(F)(F)CC2)cn1
(4,4-Difluoro-piperidin-1-yl)-[6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-pyridin-3-yl]-methanone
Rendimiento 98.0%

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

As described for example 8b, 6-(5-methyl-3-phenyl-isoxazol-4-ylmethoxy)-nicotinic acid (100 mg, 0.32 mmol) was converted, using 4,4-difluoropiperidine hydrochloride (1 M in DMF) instead of methylamine, to the title compound (131 mg, 98%) which was obtained as a light yellow gum. MS: m/e=414.4 [M+H]+.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US08846719B2uspto-grants-2014_09