Reacción #1702020

Ecuación de reacción

Ethylidenenorbornene

Butyl ether

diethylaluminumchloride

→

Dicyclopentadiene Ethylidenenorbornene

Disolventes

dicyclopentadiene

Condiciones de reacción

Tratamiento posterior

1. 1
   Otrowas then capped with a septum
2. 2
   Otropurged with nitrogen
3. 3
   workup.DISSOLUTIONto dissolve the solids

Procedimiento

Irganox™ 1010 (0.24 g, Ciba Specialty Chemical Corp, Tarrytown, N.Y.) and Irgafos™ 168 (0.72 g, Ciba) were placed in an oven-dried 125 mL Erlenmeyer flask which was then capped with a septum and purged with nitrogen. Ethylidenenorbornene (35.6 mL, 0.26 mol) was added and the mixture was stirred for several minutes to dissolve the solids. Butyl ether (2.4 mL) and 9.1 mL of a 10 vol % solution of diethylaluminumchloride in dicyclopentadiene were then added. This solution is denoted Mixture 4B.

Fuente