Reacción #1563917

ord-638e1f8b21974b7b92c2e1c74abf1fa9

Ecuación de reacción

COC(=O)C=Cc1ccc2c(c1)nc(CNC(=O)OCC1c3ccccc3-c3ccccc31)n2C
3-[2-(N-Fmoc-aminomethyl)-1methyl-1H-benzimidazol-5-yl]-acrylic acid methyl ester
C1CCNCC1
piperidine
COC(=O)C=Cc1ccc2c(c1)nc(CN)n2C
3-(2-aminomethyl-1-methyl-1H-benzimidazol-5-yl)-acrylic acid methyl ester

Disolventes

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    OtroRemoved all the solvent and piperidine under vacuum

Procedimiento

3-[2-(N-Fmoc-aminomethyl)-1methyl-1H-benzimidazol-5-yl]-acrylic acid methyl ester (43 mg, 0.176 mmol, prepared according to Example 42, step 1-3 by using appropriate starting materials) was dissolved in 10 mL of dichloromethane. The resulting solution was treated with 2.0 mL of piperidine. Removed all the solvent and piperidine under vacuum gave 3-(2-aminomethyl-1-methyl-1H-benzimidazol-5-yl)-acrylic acid methyl ester. MS(m/z): 246 [MH]+.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US09402829B2uspto-grants-2016_08