Reacción #1528391

Ecuación de reacción

1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline

cyclopentadienyltitanium trichloride

triethylamine

→

1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline cyclopentadienyltitanium dichloride

Rendimiento 177.8%

Disolventes

toluene

Condiciones de reacción

Tratamiento posterior

1. 1
   Filtraciónthe thick yellow-orange suspension was filtered
2. 2
   Otrothe filtrate evaporated to dryness

Procedimiento

To a suspension of 1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline (1.02 g, 2.5 mmol) and cyclopentadienyltitanium trichloride (0.55 g, 2.5 mmol) in toluene (20 mL) was added triethylamine (0.4 mL, 4.0 mmol) at ambient temperature. After stirring for 2 hours, the thick yellow-orange suspension was filtered, and the filtrate evaporated to dryness to afford 1.31 g (89% yield) of NMR-pure 1,3-bis(2,6-diisopropylphenyl)-iminoimidazoline cyclopentadienyltitanium dichloride.

Fuente