Reacción #1435722

Ecuación de reacción

potassium hydride

(3-trimethylsiloxy-propyl)-cyclopentadiene

→

potassium (3-trimethylsiloxypropyl)-cyclopentadienide

Rendimiento 70.0%

Disolventes

tetrahydrofurane

tetrahydrofurane

Condiciones de reacción

Tratamiento posterior

1. 1
   workup.ADDITIONis added
2. 2
   TemperaturaThe reaction is maintained
3. 3
   ConcentraciónSubsequently, the resulting suspension is concentrated to dryness
4. 4
   Otroleaving an oily solid that, when it
5. 5
   Lavadois washed with hexane
6. 6
   Otrogives a cream-coloured solid

Procedimiento

To a suspension of 0.4 g (10 mmol) of potassium hydride in tetrahydrofurane, 1.96 g (10 mmol) of a (3-trimethylsiloxy-propyl)-cyclopentadiene in tetrahydrofurane is added. The reaction is maintained under stirring for 2 hours. Subsequently, the resulting suspension is concentrated to dryness, leaving an oily solid that, when it is washed with hexane, gives a cream-coloured solid. (1.6 g, 7 mmol. Yield:70%).

Fuente