Reacción #137302

ord-258eb46a1af5427b8bd3b37d8154c2f2

Ecuación de reacción

O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]
O=C(/C=C/c1ccccc1)/C
C=Cc1ccccc1
styrene
Ic1ccccc1
Ic1ccccc1
→
COc1cc(OC)cc(OC)c1
1,3,5-trimethoxybenzene
C(=C\c1ccccc1)/c1ccccc1
Trans stilbene
C=C(c1ccccc1)c1ccccc1
1,1'-diphenylethylene

Reactantes

O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.O=C(/C=C/c1ccccc1)/C=C/c1ccccc1.[Pd].[Pd]
O=C(/C=C/c1ccccc1)/C=C/c1ccccc
C=Cc1ccccc1
styrene
Ic1ccccc1
Ic1ccccc1

Reactivos

CCN(CC)CC
triethylamine
CC(C)(C)[PH+](C(C)(C)C)C(C)(C)C.F[B-](F)(F)F
CC(C)(C)[PH+](C(C)(C)C)C(C)(C)

Disolventes

CN(C)C=O
CN(C)C=O

Condiciones de reacción

Temperatura
85°CELSIUS

Tratamiento posterior

  1. 1
    workup.ADDITION

Fuente

Styrene Mizoroki-Heck