Reacción #1361212

Ecuación de reacción

1-Amino-3-nitro-1,2,4-triazole

t-butyl hypochlorite

→

1,1'-azobis-(3-nitro-1,2,4-triazole)

Rendimiento 31.5%

Disolventes

acetonitrile

Condiciones de reacción

Tratamiento posterior

1. 1
   workup.STIRRINGThe resulting solution was stirred for 24 h, at room temperature
2. 2
   Concentraciónconcentrated in vacuo
3. 3
   Otrotriturated with isopropyl alcohol (3 mL)
4. 4
   FiltraciónThe undissolved solid was collected by filtration

Procedimiento

1-Amino-3-nitro-1,2,4-triazole (1.3 g, 10 mmol) was dissolved in 10 mL of dry acetonitrile, cooled to 0° C. with stirring under argon, and treated with t-butyl hypochlorite (1.1 g, 10 mmol) over 10 minutes. The resulting solution was stirred for 24 h, at room temperature, concentrated in vacuo, and triturated with isopropyl alcohol (3 mL). The undissolved solid was collected by filtration to give 400 mg (30%) of 1,1'-azobis-(3-nitro-1,2,4-triazole). The identity of the product was confirmed using NMR spectroscopy and X-ray diffraction.

Fuente