Reacción #1340565

Ecuación de reacción

CsF

toluene acetonitrile

→

desired ligands

Triphenylene

Condiciones de reacción

Procedimiento

1-trifluoromethanesulfonato-2-trimethylsilylbenzene (3 equivalents) is reacted with 1 equivalent of the appropriate iodoaromatic (see scheme 5a), in the presence of 5 mol % of Pd(OAc)2, 5 mol % of dppf and 4 equivalents of CsF in toluene/acetonitrile, to obtain the desired ligands of the formulae IId), IIe) and IIf).

Fuente