Reacción #1261632

Ecuación de reacción

1-methylnaphthalene

N-bromosuccinimide

benzoyl peroxide

→

1-(bromomethyl)naphthalene

Rendimiento 94.0%

Disolventes

carbon tetrachloride

Condiciones de reacción

Tratamiento posterior

1. 1
   Temperaturawhile heating
2. 2
   Temperaturarefluxing
3. 3
   OtroThe deposit was removed by filtration
4. 4
   Concentraciónthe filtrate was concentrated

Procedimiento

A mixture of 52.35 g (368.1 mmol) of 1-methylnaphthalene, 68.79 g (368.5 mmol) of N-bromosuccinimide (NBS), 0.45 g (1.86 mmol) of benzoyl peroxide (BPO) and 250 ml of carbon tetrachloride was stirred for 6 hours while heating and refluxing. The deposit was removed by filtration, and the filtrate was concentrated to obtain 84.64 g (purity: 90.4%, yield: 94%) of an oily crude product of 1-(bromomethyl)naphthalene.

Fuente