Reacción #1255206

Ecuación de reacción

Diphenyliodonium chloride

trimethyl phosphate

→

target compound

Rendimiento 81.6%

diphenyliodonium dimethylphosphonate

Rendimiento 81.6%

Condiciones de reacción

Tratamiento posterior

1. 1
   workup.DISSOLUTIONAfter the reactants were dissolved
2. 2
   Temperaturathe mixture was cooled
3. 3
   Otroto thereby yield solid matter
4. 4
   LavadoThe solid matter was washed with ether

Procedimiento

Diphenyliodonium chloride (315 mg; 1 mmol) and trimethyl phosphate (1 g) were stirred at 170° C. for 10 minutes. After the reactants were dissolved, the mixture was cooled, to thereby yield solid matter. The solid matter was washed with ether, to thereby yield 250 mg of the target compound as white crystals (yield: 81.6%). The anion content of the resultant compound was determined by ion chromatography. The chloride anion content was determined to be not greater than 10 ppm.

Fuente