Reacción #12076

ord-ebe86df30b2441388fb356c07f9e4914

Ecuación de reacción

C=CC(=O)[O-].[Na+]
sodium acrylate
CCO[Si](Cl)(OCC)OCC
chlorotriethoxysilane
→
C=CC(=O)[Si](OCC)(OCC)OCC
acryltriethoxysilane

Reactantes

C=CC(=O)[O-].[Na+]
sodium acrylate
CCO[Si](Cl)(OCC)OCC
chlorotriethoxysilane

Reactivos

Ninguno

Disolventes

C1CCOC1
THF
C1CCOC1
THF

Condiciones de reacción

Temperatura
-70°CELSIUS
Condiciones detalladas
See reaction.notes.procedure_details.

Tratamiento posterior

  1. 1
    Temperaturato warm up to room temperature
  2. 2
    OtroNaCl is removed by filtration and solution
  3. 3
    Otroevaporated to dryness

Procedimiento

6.123 g (0.0651 mol) sodium acrylate is dissolved to 25 mL THF and cooled to −70° C. 12.8 mL (0.0651 mol, 12.938 g) chlorotriethoxysilane in THF (15 mL) is added dropwise to reaction solution. The solution is stirred for over night allowing it to warm up to room temperature. NaCl is removed by filtration and solution evaporated to dryness to result clear liquid, acryltriethoxysilane.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US07098346B2uspto-grants-2006_08