Reacción #1192972

ord-48642f58e3b84aca8818938e77021646

Ecuación de reacción

F[P-](F)(F)(F)(F)F.[H+]
hexafluorophosphoric acid
[Cl-].c1ccc([I+]c2ccccc2)cc1
diphenyliodonium chloride
F[B-](F)(F)F.[H+]
fluoroboric acid
F[P-](F)(F)(F)(F)F.c1ccc([I+]c2ccccc2)cc1
diphenyliodonium hexafluorophosphate
Rendimiento 74.0%

Condiciones de reacción

Condiciones detalladas
See reaction.notes.procedure_details.

Procedimiento

The procedure of Example 1 was repeated for preparing an aromatic halonium salt using diphenyliodonium chloride. In this preparation, fluoroboric acid was replaced by 25 ml (60%) hexafluorophosphoric acid. There was obtained a 74% yield of diphenyliodonium hexafluorophosphate having a m.p. of 139°-141° C.

Fuente

DOI: 10.6084/m9.figshare.5104873.v1Patente: US04310469uspto-grants-1982_01