Reacción #1106607

Ecuación de reacción

Trifluoroacetic acid

trifluoroacethydrazide

→

1,2-bis(trifluoroacetyl)hydrazine

Disolventes

benzene

Condiciones de reacción

Tratamiento posterior

1. 1
   Temperaturathe mixture was heated
2. 2
   Temperaturaunder reflux for 2 h
3. 3
   OtroA Dean and Stark trap was fitted
4. 4
   Temperaturareflux
5. 5
   TemperaturaReflux
6. 6
   Otrowas continued in the absence of the Dean and Stark trap (3 h)
7. 7
   Otro(20 h)
8. 8
   FiltraciónThe resulting white solid was collected by filtration
9. 9
   Otrodried in vacuum

Procedimiento

Trifluoroacetic acid (7.6 mL, 0.1 mol) was added to a stirred solution of trifluoroacethydrazide (12.8 g, 0.1 mol) in benzene (100 mL) and the mixture was heated under reflux for 2 h. A Dean and Stark trap was fitted, and reflux was continued for 3 h. Reflux was continued in the absence of the Dean and Stark trap (3 h) and then with the trap refitted (20 h). The resulting white solid was collected by filtration, dried in vacuum and identified as 1,2-bis(trifluoroacetyl)hydrazine (16.5 g, 73%). M.p. 173-175° C.

Fuente