Reaction #992679

Reaction equation

Hydrazine monohydrate

Trifluoroacetic acid

→

Hydrazinium TFA

Solvents

water

Conditions

Workup

1. 1
   workup.STIRRINGthe reaction was stirred at room temperature overnight
2. 2
   OtherThe water was removed in vacuo
3. 3
   Temperaturewith heating to 80° C.
4. 4
   Otheryielding product as a colorless liquid

Procedure

Hydrazine monohydrate (4.41 ml, 90.9 mmol) was added via syringe to a 250-ml round-bottom flask containing 50 ml of distilled water with stirring at room temperature. Trifluoroacetic acid (7.0 ml, 90.9 mmol) was added via syringe and the reaction was stirred at room temperature overnight. The water was removed in vacuo with heating to 80° C., yielding product as a colorless liquid.

Source