Reaction #95322

ord-cc44b03cebb44e549c4cdf1dc72accfc

Reaction equation

CCCCCCCCCCCCCCCCCCN1C(C)(C)CC(O)CC1(C)C
1-n-octadecyl-2,2,6,6-tetramethyl-4-piperidinol
CCC1=C(CC)C2CCC1C2
diethyl bicyclo [2.2.1]hept-5-ene
→
CCCCCCCCCCCCCCCCCCN1C(C)(C)CC(C2=C(C3CC(C)(C)N(CCCCCCCCCCCCCCCCCC)C(C)(C)C3)C3CCC2C3)CC1(C)C
bis-(1-n-octadecyl-2,2,6,6-tetramethyl-4-piperidyl) bicyclo[2.2.1]hept-5-ene

Reactants

CCCCCCCCCCCCCCCCCCN1C(C)(C)CC(O)CC1(C)C
1-n-octadecyl-2,2,6,6-tetramethyl-4-piperidinol
CCC1=C(CC)C2CCC1C2
diethyl bicyclo [2.2.1]hept-5-ene
—
exo-2,3-dicarboxylate

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Procedure

In an analogous manner is also reacted diethyl bicyclo [2.2.1]hept-5-ene-endo,exo-2,3-dicarboxylate with 1-n-octadecyl-2,2,6,6-tetramethyl-4-piperidinol to give wax-like bis-(1-n-octadecyl-2,2,6,6-tetramethyl-4-piperidyl) bicyclo[2.2.1]hept-5-ene-endo,exo-2,3-dicarboxylate. (Example 9)

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04344877uspto-grants-1982_08