Reaction #95293

ord-c682168609e84d10b8592d61cc4f19f5

Reaction equation

CCCC(C)(C)CC(O)/C=C/I
5,5-dimethyl-1-iodo-trans-1-octen-3-ol
BrC(c1ccccc1)(c1ccccc1)c1ccccc1
triphenylmethyl bromide
→
CCCC(C)(C)CC(/C=C/I)OC(c1ccccc1)(c1ccccc1)c1ccccc1
title compound
CCCC(C)(C)CC(/C=C/I)OC(c1ccccc1)(c1ccccc1)c1ccccc1
5,5-dimethyl-1-iodo-3-triphenylmethoxy-trans-1-octene

Reactants

CCCC(C)(C)CC(O)/C=C/I
5,5-dimethyl-1-iodo-trans-1-octen-3-ol
BrC(c1ccccc1)(c1ccccc1)c1ccccc1
triphenylmethyl bromide

Reagents

None

Conditions

Detailed conditions
See reaction.notes.procedure_details.

Workup

  1. 1
    Otherof pyridine and purification on Florisil®

Procedure

Treatment of 6.0 g. of 5,5-dimethyl-1-iodo-trans-1-octen-3-ol (Example 1000) with 6.9 g. of triphenylmethyl bromide in 30 ml. of pyridine and purification on Florisil®, all as described in Example 728 gives the title compound.

Source

DOI: 10.6084/m9.figshare.5104873.v1Patent: US04343949uspto-grants-1982_08